Rearrangement of 1-Methyl-2-(substituted-phenyl)piperidinium 1-Methylides in a Neutral Medium

DOI: 10.1021/jo00265a022

Source and publish data:

Journal of Organic Chemistry p. 836 - 840 (1989)

Update date:2022-08-05

Topics:

Authors:

Shirai, Naohiro

Sumiya, Fumihiko

Sato, Yoshiro

Hori, Mikiko

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Article abstract of DOI:10.1021/jo00265a022

Reaction of 1-methyl-1-<(trimethylsilyl)methyl>-2-(substituted-phenyl)piperidinium iodides (3) with cesium fluoride in DMF gave good yields of 2-methyl-1,3,4,5,6,11a-hexahydro-2H-2-benzazonine derivatives (5), which are regarded as unstable intermediates

Full text of DOI:10.1021/jo00265a022

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Product name:2-(4-Methoxy-phenyl)-1-trimethylsilanylmethyl-piperidine

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