Rearrangement of 1-Methyl-2-(substituted-phenyl)piperidinium 1-Methylides in a Neutral Medium

DOI: 10.1021/jo00265a022

Source and publish data:

Journal of Organic Chemistry p. 836 - 840 (1989)

Update date:2022-08-05

Topics:

Authors:

Shirai, Naohiro

Sumiya, Fumihiko

Sato, Yoshiro

Hori, Mikiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00265a022

Reaction of 1-methyl-1-<(trimethylsilyl)methyl>-2-(substituted-phenyl)piperidinium iodides (3) with cesium fluoride in DMF gave good yields of 2-methyl-1,3,4,5,6,11a-hexahydro-2H-2-benzazonine derivatives (5), which are regarded as unstable intermediates

Full text of DOI:10.1021/jo00265a022

Products guided by the article

Product name:2-(4-Methoxy-phenyl)-1-trimethylsilanylmethyl-piperidine

Cas No:118577-01-8

R&D Labs maybe for 118577-01-8

WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone
Phantom-pharma

Contact:

Address:
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China

Relevant to this article

Cu-catalyzed direct ortho-chlorination/-oxygenation of aryls: Switching of oxidant, control the diversity of products

Doi:10.1016/j.tetlet.2018.11.071
(2019)
Metal-Free Aryl Cross-Coupling Directed by Traceless Linkers

Doi:10.1002/chem.201903582
(2019)
Identification and optimisation of a novel series of pyrimidine based cyclooxygenase-2 (COX-2) inhibitors. Utilisation of a biotransformation approach

Doi:10.1016/j.bmcl.2009.02.089
(2009)
Cyclometallated platinum compounds with N-benzylidenebenzylamines bearing trifluoromethyl groups. Crystal structure of [PtMe{3-(CF₃) C₆H₃CH=NCH₂Ph(PPh₃)]

Doi:10.1016/S0277-5387(97)00452-X
(1998)
Memory devices based on functionalized copolymers exhibiting a linear dependence of switch threshold voltage with the pendant nitro-azobenzene moiety content change

Doi:10.1039/c2jm33426g
(2012)
Synthesis and biological evaluation of new tetrahydronaphthalene derivatives as thromboxane receptor antagonists

Doi:10.1016/S0960-894X(98)00220-0
(1998)

Article Doi