Chemical Communications p. 15206 - 15208 (2014)
Update date:2022-09-26
Topics:
Sai, Masahiro
Akakura, Matsujiro
Yamamoto, Hisashi
In the silyl Lewis acid-promoted Mukaiyama aldol reaction, the steric and electronic properties of the silyl group on the silyl Lewis acid influence the reaction mechanism and product distribution. When super silyl triflates such as (TMS)3SiOTf and (TES)3SiOTf are used as Lewis acids, the silyl group of the silyl enol ether chemoselectively transfers to the product. The mechanistic details have been investigated using density functional theory (DFT) calculations.
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