Zinc Chloride Catalyzed Rearrangements of 1,2-Dialkynyl-1,2-dihydroxy-3,6-dimethoxy-3,5-cyclohexadienes to Bicyclooctadienones and Bicyclooctadienones

DOI: 10.1021/jo00267a028

Source and publish data:

Journal of Organic Chemistry p. 1379 - 1383 (1989)

Update date:2022-08-03

Topics:

Authors:

Fernandez, Mario

Chang, Shoumo

Ziller, Joseph

Doedens, Robert J.

Moore, Harold W.

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Article abstract of DOI:10.1021/jo00267a028

Reported here are unusual rearrangements of 1 and 3 to the bicyclooctadienones 2 and 4.This was accomplished when a carbon tetrachloride solution of respectively 1 and 3 was refluxed for 2 h in the presence of zinc chloride.The structure and stereochemist

Full text of DOI:10.1021/jo00267a028

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