On the first Insertion of α-olefins in hafnium pyridyl-amido polymerization catalysts

DOI: 10.1021/om900705v

Source and publish data:

Organometallics p. 5445 - 5458 (2009)

Update date:2022-07-31

Topics:

Authors:

Zuccaccia, Cristiano

Busico, Vincenzo

Cipullo, Roberta

Talarico, Giovanni

Froese, Robert D.J.

Vosejpka, Paul C.

Hustad, Phillip D.

Macchioni, Alceo

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Article abstract of DOI:10.1021/om900705v

Reactions of [{N-,N,C_naphthy1}HfMe][MeB(C₆F5) ₃] (2) precatalyst with a series of a-olefins have been investigated in order to intercept the active polymerization species generated by an in situ modification of the precurs

Full text of DOI:10.1021/om900705v

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Product name:[Hf(CHCHC₅H₄N)(((CH₃)2CH)2C₆H₃NCH(C₆H₄CH(CH₃)2)(C₅H₃N)C₁₀H₆CH₂CHC₅H₄N)]⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-)=C₇₀H₅₄HfN₄BF₁₅

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