Journal of Organic Chemistry p. 1006 - 1012 (1989)
Update date:2022-08-02
Topics:
Rachon, Janusz
Goedken, V.
Walborsky, H. M.
The syntheses and the establishment of the absolute configurations of chiral (S)-(+)-2-bromodibenzobicyclo<2.2.2>octadiene-2-carboxylic acid (1) and (1S,2S,5S)-(-)-exo-2-methoxydibenzobicyclo<3.2.1>octadiene-1-carboxylic acid (2) and their derivatives are described.The rearrangement of 1 to 2 is discussed in terms of a nonclassical ion intermediate in light of the observed stereochemistry.
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