Organometallics p. 893 - 894 (1987)
Update date:2022-09-26
Topics:
Horton
Schrock
Freudenberger
The reaction between ReO3(OSiMe3) and ArNCO (Ar = 2,6-diisopropylphenyl) yields what is believed to be a mixture of Re2Ox (NAr)7-x complexes, one of which, Re2O2(NAr)5 (1), can be isolated in ～30% yield. Pure 1, or the crude mixture, when treated with 3 equiv of py·HCl (py = pyridine) yields Re(NAr)2(Py)Cl3 (2) in 70-80% isolated yield vs. ReO3(OSiMe3). Addition of 0.65 equiv of Zn(CH2-t-Bu)2 to 2 yields Re(NAr)2(CH2-t-Bu)Cl2 (3) in 75% isolated yield. Dehydrohalogenation of 3 with DBU yields Re(NAr)2(CH-t-Bu)Cl (4) virtually quantitatively, which can be treated with LiOR (OR = OCH(C-F3)2 or O-2,6-C6H3-i-Pr2) to give relatives of the type Re-(NAr)2(CH-t-Bu)(OR) (5). Compounds 4 and 5 are very soluble, presumably monomeric, 18-electron complexes that do not react with cis-2-pentene or norbornene.
Jiangxi Hessence Chemicals Co., Ltd.
Contact:+86 796 3511924
Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Changzhou Sunsheng Chem Co., Ltd
Contact:+1-(989)-854-0648
Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
Contact:+86-21-38228826
Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
taicang liyuan chemical co,.ltd
website:http://www.tcliyuanchem.com/productse.php
Contact:86-512-53539583
Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Baicao Pharmaceutical Co., Ltd.
website:http://www.jxbaicao.com
Contact:+86-796-8113329
Address:It (country) economic and technological development zone of the jinggang mountains
Doi:10.1071/CH09058
(2009)Doi:10.1139/v65-140
(1965)Doi:10.1016/j.bmc.2009.08.023
(2009)Doi:10.1016/j.tet.2009.08.043
(2009)Doi:10.1039/b910192f
(2009)Doi:10.1021/jo00270a042
(1989)
