Organic Letters p. 5370 - 5373 (2010)
Update date:2022-09-26
Topics:
Wang, Jianping
Tong, Xiaofeng
Xie, Xiaomin
Zhang, Zhaoguo
A RhCl(PPh3)3-catalyzed halogen-exchange reaction between allyl and alkyl halides with β-H atoms was observed. The possible mechanism of the reaction involves oxidative addition and reductive elimination of the C(sp3)-X bonds, which is not common in organometallic chemistry.
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