FIRST TOTAL SYNTHESIS OF (-)-FUMITREMORGIN

DOI: 10.1016/S0040-4020(01)90342-4

Source and publish data:

Tetrahedron p. 1991 - 2000 (1988)

Update date:2022-07-30

Topics:

Authors:

Hermkens, Pedro H. H.

Plate, Ralf

Ottenheijm, Harry C. J.

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Article abstract of DOI:10.1016/S0040-4020(01)90342-4

The first total synthesis of the tremorgic mycotoxin fumitremorgin C (1a) employing 6-methoxy-N-hydroxytryptophan (5a) is presented.Our approach features formation of the nitrone (6a), stereoselective cycloaddition to yield (7a), ring opening and coupling

Full text of DOI:10.1016/S0040-4020(01)90342-4

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