Dissecting competitive mechanisms: Thionation vs. cycloaddition in the reaction of thioisomuenchnones with isothiocyanates under microwave irradiation

DOI: 10.1021/jo900960a

Source and publish data:

Journal of Organic Chemistry p. 7644 - 7650 (2009)

Update date:2022-07-30

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Authors:

Cantillo, David

Avalos, Martin

Babiano, Reyes

Cintas, Pedro

Jimenez, Jose L.

Light, Mark E.

Palacios, Juan C.

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Article abstract of DOI:10.1021/jo900960a

(Chemical Equation Presented) This paper documents in detail the reaction of 1,3-thiazolium-4-olates (thioisomuenchnones) with aryl isothiocyanates. Having demonstrated with a chiral model that thionation occurs under these conditions to provide 1,3-thiaz

Full text of DOI:10.1021/jo900960a

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