RESOLUTION AND DETERMINATION OF ENANTIOMERIC EXCESSES OF CHIRAL ALDEHYDES VIA CHIRAL IMIDAZOLIDINES

DOI: 10.1016/0040-4039(88)85258-4

Source and publish data:

Tetrahedron Letters p. 2677 - 2680 (1988)

Update date:2022-08-05

Topics:

Authors:

Mangeney, P.

Alexakis, A.

Normant, J. F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)85258-4

Enantiomeric purity of chiral aldehydes was determined by NMR analysis of derived imidazolidines.The diastereomeric imidazolidines were easily separated by silica gel column and converted into enantiomerically pure aldehyde by acid hydrolysis.

Full text of DOI:10.1016/0040-4039(88)85258-4

Products guided by the article

Product name:3-[3-((4S,5S)-1,3-Dimethyl-4,5-diphenyl-imidazolidin-2-yl)-oxiranyl]-propionic acid methyl ester

Cas No:119181-96-3

R&D Labs maybe for 119181-96-3

KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Guangzhou Shiny Co., Ltd.

website:https://www.sinoshiny.com/products

Contact:+86-20-62802632;62802633

Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Hubei Xiangxi Chemical Industry Co.,Ltd

Contact:+86-710-3454830

Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China

Relevant to this article

(2S)-1-(arylacetyl)-2-(aminomethyl)piperidine derivatives: Novel, highly selective κ opioid analgesics

Doi:10.1021/jm00105a061
(1991)
Preparation of some angularly substituted and highly functionalized quinolizidines as building blocks for the synthesis of various alkaloids and related scaffolds of medicinal interest

Doi:10.1016/j.tet.2009.07.067
(2009)
SILICON-DIRECTED BECKMANN FRAGMENTATION

Doi:10.1016/S0040-4020(01)81693-8
(1988)
Structure-based optimization of potent and selective inhibitors of the tyrosine kinase erythropoietin producing human hepatocellular carcinoma receptor B4 (EphB4)

Doi:10.1021/jm9009444
(2009)
Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides: An avenue for asymmetric oxidation using Cinchona organocatalysis

Doi:10.1039/b908717f
(2009)
Highly efficient synthesis of homoallylamines from aldimines with allylstannane promoted by MgI₂ etherate

Doi:10.3184/030823410X12756737135354
(2010)

Article Doi