RESOLUTION AND DETERMINATION OF ENANTIOMERIC EXCESSES OF CHIRAL ALDEHYDES VIA CHIRAL IMIDAZOLIDINES

DOI: 10.1016/0040-4039(88)85258-4

Source and publish data:

Tetrahedron Letters p. 2677 - 2680 (1988)

Update date:2022-08-05

Topics:

Authors:

Mangeney, P.

Alexakis, A.

Normant, J. F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)85258-4

Enantiomeric purity of chiral aldehydes was determined by NMR analysis of derived imidazolidines.The diastereomeric imidazolidines were easily separated by silica gel column and converted into enantiomerically pure aldehyde by acid hydrolysis.

Full text of DOI:10.1016/0040-4039(88)85258-4

Products guided by the article

Product name:3-[3-((4S,5S)-1,3-Dimethyl-4,5-diphenyl-imidazolidin-2-yl)-oxiranyl]-propionic acid methyl ester

Cas No:119181-96-3

R&D Labs maybe for 119181-96-3

HangZhou HuaYe Chemical Technology Co.,Ltd

Contact:+86-13505815007

Address:hangzhou
SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Wuhan Biet Co., Ltd

website:http://www.biet.com.cn/

Contact:+86-27-8369 8488

Address:No. 6, Building 21, China Merchants Fanwang, Sixin North Road, Hanyang District, Wuhan City, Hubei Province
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.

Relevant to this article

(2S)-1-(arylacetyl)-2-(aminomethyl)piperidine derivatives: Novel, highly selective κ opioid analgesics

Doi:10.1021/jm00105a061
(1991)
Preparation of some angularly substituted and highly functionalized quinolizidines as building blocks for the synthesis of various alkaloids and related scaffolds of medicinal interest

Doi:10.1016/j.tet.2009.07.067
(2009)
SILICON-DIRECTED BECKMANN FRAGMENTATION

Doi:10.1016/S0040-4020(01)81693-8
(1988)
Structure-based optimization of potent and selective inhibitors of the tyrosine kinase erythropoietin producing human hepatocellular carcinoma receptor B4 (EphB4)

Doi:10.1021/jm9009444
(2009)
Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides: An avenue for asymmetric oxidation using Cinchona organocatalysis

Doi:10.1039/b908717f
(2009)
Highly efficient synthesis of homoallylamines from aldimines with allylstannane promoted by MgI₂ etherate

Doi:10.3184/030823410X12756737135354
(2010)

Article Doi