Stereomutation of 7-Tropylionorbornane, 2-Tropyliobicyclooctane, and 2-Tropylioadamantane: Evidence for the Intermediacy of Heptafulvenes

DOI: 10.1021/jo00003a028

Source and publish data:

Journal of Organic Chemistry p. 1052 - 1058 (1991)

Update date:2022-07-30

Topics:

Authors:

Ikai, Keizo

Takeuchi, Ken'ichi

Kinoshita, Tomomi

Haga, Ken'ichi

Komatsu, Koichi

Okamoto, Kunio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00003a028

The perchlorates of 7-tropylionorbornane (3), 2-tropyliobicyclo<2.2.2>octane (4), and 2-tropylioadamantane (5) were found to undergo stereomutation in acetonitrile at 25-85 deg C, as evidenced by following the change in the 13C NMR spectra of their deuter

Full text of DOI:10.1021/jo00003a028

Products guided by the article

Product name:5-(ethylenedioxy)-2-phenylbicyclo<2.2.2>octan-2-ol

Cas No:1192365-33-5

R&D Labs maybe for 1192365-33-5

Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Wuhan Konberd Biotech Co., Ltd.

Contact:+86-27-87205925

Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China

Relevant to this article

Solvent-free synthesis of 1, 3-diphenyl-5-arylpyrazole derivatives

Doi:10.2174/157017809788681383
(2009)
Ligand-Assisted Electron Transfer from the Triplet State of Zinc Tetraphenylporphyrin to 1,4-Benzoquinone

Doi:10.1021/j100346a049
(1989)
Cross-Dehydrogenative Coupling of Tertiary Amines and Terminal Alkynes Catalyzed by Copper Nanoparticles on Zeolite

Doi:10.1002/adsc.201500787
(2015)
Mononuclear Titanium Complexes That Contain Aminopyridinato Ligands

Doi:10.1021/ic951177a
(1996)
Mechanism of Mukaiyama-Michael reaction of ketene silyl acetal: Electron transfer or nucleophilic addition?

Doi:10.1021/jo9512968
(1996)
26. A ¹H-NMR spectroscopic investigation of the conformation of the acetamido group in some derivatives of N-acetyl-D-allosamine and -D-glucosamine

Doi:10.1002/hlca.19960790127
(1996)

Article Doi