Stereomutation of 7-Tropylionorbornane, 2-Tropyliobicyclooctane, and 2-Tropylioadamantane: Evidence for the Intermediacy of Heptafulvenes

DOI: 10.1021/jo00003a028

Source and publish data:

Journal of Organic Chemistry p. 1052 - 1058 (1991)

Update date:2022-07-30

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Authors:

Ikai, Keizo

Takeuchi, Ken'ichi

Kinoshita, Tomomi

Haga, Ken'ichi

Komatsu, Koichi

Okamoto, Kunio

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Article abstract of DOI:10.1021/jo00003a028

The perchlorates of 7-tropylionorbornane (3), 2-tropyliobicyclo<2.2.2>octane (4), and 2-tropylioadamantane (5) were found to undergo stereomutation in acetonitrile at 25-85 deg C, as evidenced by following the change in the 13C NMR spectra of their deuter

Full text of DOI:10.1021/jo00003a028

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