Tetrahedron p. 3869 - 3888 (1988)
Update date:2022-07-31
Topics:
Molander, Gary A.
Andrews, Steven W.
Use of chelation control to direct the stereochemical outcome of intramolecular additions of allylsilanes to β-dicarbonyl substrates is described.Excellent diastereoselectivity is achieved by titanium tetrachloride promoted cyclization of a wide variety o
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