VINYL TRIFLUOROSULFONATES IN THE CARBOPALLADATION OF ALLENIC HYDROCARBONS

DOI: 10.1016/S0040-4039(00)80424-4

Source and publish data:

Tetrahedron Letters p. 4089 - 4092 (1988)

Update date:2022-08-05

Topics:

Authors:

Friess, Beatrice

Cazes, Bernard

Gore, Jacques

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Article abstract of DOI:10.1016/S0040-4039(00)80424-4

The palladium-catalyzed reaction of an enol triflate, an allenic hydrocarbon, and the anion of dimethyl malonate leads to conjugated dienes 1 in good yield.No isomerization is observed when this reaction is run with both triflates of 2-methylcyclohexanone

Full text of DOI:10.1016/S0040-4039(00)80424-4

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