Phosphorus, Sulfur and Silicon and the Related Elements p. 930 - 946 (2010)
Update date:2022-08-04
Topics: Synthesis Thermolysis 1,3-Diketones
Nakaiida, Shoho
Kato, Shinzi
Niyomura, Osamu
Ishida, Masaru
Ando, Fumio
Koketsu, Jugo
A series of Te-1-acylmethyl carbotelluroates was prepared in good isolated yields from the reaction of potassium carbotelluroates with -haloketones in acetonitrile. Thermolysis of the telluroesters afforded vinyl esters in 20-50% yields, while treatment of the carbotellurorates with potassium t-butanolate led to 1,3-diketones in 30-75% yields with the liberation of black tellurium. The reaction of potassium carbotelluroates with -haloaceto oximes gave O-acyl oximes in 50-70% yields via Te-1-iminomethylcarbotelluroates. Copyright Taylor & Francis Group.
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