PALLADIUM-CATALYSED REGIOSELECTIVE REACTIONS OF SILYL-SUBSTITUTED ALLYLIC CARBONATES AND VINYL EPOXIDE

DOI: 10.1016/S0040-4039(00)80091-X

Source and publish data:

Tetrahedron Letters p. 343 - 346 (1988)

Update date:2022-08-02

Topics:

Authors:

Tsuji, Jiro

Yuhara, Masami

Minato, Makoto

Yamada, Hisao

Sato, Fumie

Kobayashi, Yuichi

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Article abstract of DOI:10.1016/S0040-4039(00)80091-X

Palladium-catalysed reaction of α-substituted γ-trimethylsilylated allylic carbonates with carbonucleophiles took place regioselectively at the α-carbon.Reaction of formic acid took place at γ-carbon to afford allylic silanes.Methyl acetoacetate attacked

Full text of DOI:10.1016/S0040-4039(00)80091-X

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