Tetrahedron Letters p. 7549 - 7552 (1990)
Update date:2022-08-04
Topics:
Parry, Ronald J.
Haridas, Kochat
Jong, Randall De
Johnson, Carl R.
Evidence for the intermediacy of a 4β-hydroxymethyl-1α,2α,3α-trihydroxycyclopentanetriol (5 or 6) in the biosynthesis of the nucleoside antibiotic aristeromycin (1) has been obtained by administration of doubly-labeled forms of D-glucose to the fermentation broth of Streptomyces citricolor followed by trapping of the tetrol 5 using isotope dilution methods.
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