HIGHLY EFFICIENT TOTAL SYNTHESIS OF MANOALIDE AND SECO-MANOALIDE VIA Pd(0) CATALYZED COUPLING OF ALLYLHALIDE WITH CO AND 2-SILYL-4-STANNYLFURAN

DOI: 10.1016/S0040-4039(00)86680-0

Source and publish data:

Tetrahedron Letters p. 1173 - 1176 (1988)

Update date:2022-07-30

Topics:

Authors:

Katsumura, Shigeo

Fujiwara, Shinya

Isoe, Sachihiko

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Article abstract of DOI:10.1016/S0040-4039(00)86680-0

Total synthesis of manoalide and seco-manoalide from an allylchloride derivative was achieved by 6 steps in 56.4percent overall yield by Pd(0) catalyzed coupling with CO and 2-trimethylsilyl-4-tributylstannylfuran followed by chemoselective oxidation of 2-trimethylsilylfuran with ¹O2.

Full text of DOI:10.1016/S0040-4039(00)86680-0

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