HIGHLY EFFICIENT TOTAL SYNTHESIS OF MANOALIDE AND SECO-MANOALIDE VIA Pd(0) CATALYZED COUPLING OF ALLYLHALIDE WITH CO AND 2-SILYL-4-STANNYLFURAN

DOI: 10.1016/S0040-4039(00)86680-0

Source and publish data:

Tetrahedron Letters p. 1173 - 1176 (1988)

Update date:2022-07-30

Topics:

Authors:

Katsumura, Shigeo

Fujiwara, Shinya

Isoe, Sachihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)86680-0

Total synthesis of manoalide and seco-manoalide from an allylchloride derivative was achieved by 6 steps in 56.4percent overall yield by Pd(0) catalyzed coupling with CO and 2-trimethylsilyl-4-tributylstannylfuran followed by chemoselective oxidation of 2-trimethylsilylfuran with ¹O2.

Full text of DOI:10.1016/S0040-4039(00)86680-0

Products guided by the article

Product name:(3Z,7E)-4-Dimethoxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-1-(5-trimethylsilanyl-furan-3-yl)-deca-3,7-dien-1-ol

Cas No:119987-32-5

R&D Labs maybe for 119987-32-5

NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
Hebei Tete Trade Co., Ltd.

Contact:86-311-83160559

Address:shijiazhuang
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China

Relevant to this article

IDENTIFICATION OF DERIVATIVES OF 2H-CHROMENES AND THEIR ACYCLIC TAUTOMERIC FORMS IN THE GAS PHASE BY MASS SPECTROMETRY

Doi:10.1007/BF00475592
(1988)
Structural evolution study of substituted wustites Fe_1-z-y(Ca, Mg)_yO

Doi:10.1016/0022-3697(90)90075-Q
(1990)
Ring expansion of oxyglycals. Synthesis and conformational analysis of septanoside-containing trisaccharides

Doi:10.1021/jo901945e
(2010)
Spiro-Fused 2,5-Cyclohexadienones from the Thermal 1,3-Alkyl Migrations of Quinol Vinyl Ethers. A Strategy for Conversion of a Carbonyl Carbon to a Quaternary Carbon

Doi:10.1021/jo00283a035
(1989)
Assembly of heteroleptic copper complexes with silver salts: from discrete trinuclear complexes to infinite networks

Doi:10.1021/ic902057d
(2010)
BIO-ORGANIC SYNTHESIS OF OPTICALLY ACTIVE CYANOHYDRINS AND ACYLOINS

Doi:10.1016/S0040-4039(00)80529-8
(1988)

Article Doi