Asymmetric [4+2] cycloadditions employing 1,3-dienes derived from (R)-4-t-butyldimethyl-silyloxy-2-cyclohexen-1-one

DOI: 10.1016/j.tetlet.2009.09.055

Source and publish data:

Tetrahedron Letters p. 6621 - 6623 (2009)

Update date:2022-08-04

Topics:

Authors:

Hua, Zhengmao

Chen, Lei

Mei, Yan

Jin, Zhendong

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Article abstract of DOI:10.1016/j.tetlet.2009.09.055

1,3-Dienes derived from (R)-4-t-butyldimethylsilyloxy-2-cyclohexen-1-one react with activated dienophiles to form predominately (or sometimes exclusively) syn/endo products. These controlled [4+2] cycloadditions increase the asymmetric complexity from one

Full text of DOI:10.1016/j.tetlet.2009.09.055

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