REDUCTION OF ACROLEIN DIALKYL ACETALS WITH CrCl2. γ-ALKOXY SUBSTITUTED ALLYLIC CHROMIUM REAGENTS FOR SELECTIVE SYNTHESIS OF erythro-1,2-DIOLS.

DOI: 10.1016/S0040-4039(00)80732-7

Source and publish data:

Tetrahedron Letters p. 5263 - 5266 (1988)

Update date:2022-08-04

Topics:

Authors:

Takai, Kazuhiko

Nitta, Kenji

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)80732-7

Treatment of an aldehyde in THF at -30 deg C with a reagent derived by reduction of acrolein dialkyl acetal with CrCl2 in the presence of Me3SiI gave 1,2-erythro-3,4-butene-1,2-diol derivatives selectively.

Full text of DOI:10.1016/S0040-4039(00)80732-7

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