Canadian Journal of Chemistry p. 1341 - 1347 (1996)
Update date:2022-08-02
Topics:
Bosc, Jean-Jacques
Jarry, Christian
Ouhabi, Jamal
Laguerre, Michel
Carpy, Alain
The reaction of some 2-amino-2-oxazolines with isocyanates and arylisothiocyanates yields 3-monosubstituted or 2,3-disubstituted 2-iminooxazolidines depending on the experimental conditions and on the nature of the electrophile reactants. The structures of a mono- and a disubstituted derivative were established by X-ray analysis. The chemical behaviour of the compounds was investigated by molecular and quantum mechanics calculations. An intramolecular transposition during the second step of the reaction was found.
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