1,6 ADDITION OF CARBANIONIC REAGENTS TO 10-METHYL HEXAHYDRONAPHTHALENONE.

DOI: 10.1016/S0040-4020(01)86147-0

Source and publish data:

Tetrahedron p. 4457 - 4462 (1988)

Update date:2022-08-02

Topics:

Authors:

Hatzigrigoriou, Evagelia

Roux-Schmitt, Marie-Claude

Wartski, Lya

Seyden-Penne, Jacqueline

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Article abstract of DOI:10.1016/S0040-4020(01)86147-0

1,6 addition of carbanionic reagents to bicyclic dienone 1 requires anionic activation: according to the acidity of the corresponding carbon acids, good yields in 7α-adducts can be obtained either in THF-HMPA with nBuLi or tBuOK as bases or under solid-li

Full text of DOI:10.1016/S0040-4020(01)86147-0

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