Inversion Topologies of (2,1,4)Cyclophanes: Tethering Effects on Host-Cavity Stereodynamics

DOI: 10.1021/ja00192a023

Source and publish data:

Journal of the American Chemical Society p. 3640 - 3651 (1989)

Update date:2022-08-05

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Authors:

Brown, Alan B.

Whitlock, Howard W.

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Article abstract of DOI:10.1021/ja00192a023

The title compounds 4 (n = 3-11; formally, the diesters of diacid 11 with various α,ω-diols) have been prepared; their ring-inversion barriers were measured by dynamic NMR.Diesters of 11 with 6,6-dimethylundecane-1,11-diol and 2-<(tert-butyldimethylsilyl)

Full text of DOI:10.1021/ja00192a023

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