Carbohydrate Research p. 11 - 18 (1988)
Update date:2022-07-30
Topics:
Koenig, Wilfried A.
Mischnick-Luebbecke, Petra
Brassat, Baerbel
Lutz, Sabine
Wenz, Gerhard
Pentylated cyclomaltohexaose ( α-cyclodextrin ) can be used as a chiral stationary phase for cappilary g.l.c. in the range 40 deg to > 200 deg.Strong enantioselective molecular interactions are observed towards trifluoroacetylated carbohydrates, methyl glycosides, 1,4- and 1,5-anhydroalditols, polyols, and polyhydroxy acid methyl esters.Base-line resolution of enantiomers is achieved after only a few minutes.
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Doi:10.1021/ja907716f
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