Thermal rearrangement of thiocarbonyl-stabilised triphenylphosphonium ylides leading to (Z)-1-diphenylphosphino-2-phenylsulfenylalkenes

DOI: 10.1039/b913107h

Source and publish data:

Chemical Communications p. 7381 - 7383 (2009)

Update date:2022-08-04

Topics:

Authors:

Alan Aitken

Dawson, Graham

Keddie, Neil S.

Kraus, Helmut

Slawin, Alexandra M. Z.

Wheatley, Joanne

Woollins, J. Derek

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Article abstract of DOI:10.1039/b913107h

While thermolysis of thiocarbonyl-stabilised phosphonium ylides generally results in extrusion of Ph₃PS to give alkynes, those with a PCH function instead undergo a novel P to S transfer of a phenyl group to give (Z)-configured 1-phosphino-2-su

Full text of DOI:10.1039/b913107h

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