Journal of Organometallic Chemistry p. 171 - 180 (1988)
Update date:2022-09-26
Topics:
Weiderbruch, Manfred
Schaefers, Karen
Pohl, Siegfried
Saak, Wolfgang
Peters, Karl
Schnering, Hans Georg von
Treatment of tin tetrachloride with 2,4,6-tri-t-butylphenyllithium (supermesityllithium, 1) in a 1/2 molar ratio, by rearrangement of one supermesityl group leads to dichloro<2-methyl-2(3,5-di-t-butylphenyl)propyl>supermesitylstannane (2).However, addition of 1 to an excess of tin tetrachloride yields dichlorodisupermesitylstannane (3) as the expected transarylation product.The structures of 2 and 3 were confirmed by X-ray crystallography.
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Doi:10.1016/S0040-4020(01)86234-7
(1988)Doi:10.1002/ejoc.200900814
(2009)Doi:10.1080/00397911.2011.585732
(2012)Doi:10.1002/anie.201510132
(2016)Doi:10.1016/0022-328X(88)80099-8
(1988)Doi:10.1002/anie.201611845
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