Journal of the Chemical Society. Perkin transactions I p. 3399 - 3406 (1988)
Update date:2022-07-30
Topics:
Johnson, Graham P.
Marples, Brian A.
The lack of regioselectivity of photorearrangement of the title spiro-oxaziridines in wich the N-substituent is syn to the aromatic ring suggests that the first formed N-O-bond-cleaved species has a significant lifetime allowing rotation (inversion) to complete with rearrangement.The energy barrier to ring inversion of the title tetrahydro-1-benzazepin-2-ones is significantly influenced by the steric interaction between the N-substituent and the peri hydrogen atom.
View MoreContact:086-027-83820093
Address:16#luojiashan, wuchang district
Changsha Goomoo Chemical Technology Co.Ltd
Contact:+86-731-82197655
Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Contact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Jiangsu Hualun Chemical Industry Co., Ltd
website:http://www.hualunchem.com
Contact:+86-0514-86464168 86507985
Address:39# Middle Renmin Road, Dinghuo Town
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd
Contact:+86-536-8566856
Address:Shouguang,Shandong,China
Doi:10.1021/om00160a018
(1990)Doi:10.1016/j.tetlet.2017.07.102
(2017)Doi:10.1021/jo902375k
(2010)Doi:10.1134/S1070427209080217
(2009)Doi:10.1021/ja909555d
(2010)Doi:10.1016/S0022-328X(00)00865-2
(2001)