SmI2-mediated dialdehyde 'radical then aldol' cyclization cascades: a feasibility study

DOI: 10.1016/j.tet.2009.09.035

Source and publish data:

Tetrahedron p. 10816 - 10829 (2009)

Update date:2022-08-05

Topics:

Authors:

Helm, Matthew D.

Da Silva, Madeleine

Sucunza, David

Helliwell, Madeleine

Procter, David J.

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Article abstract of DOI:10.1016/j.tet.2009.09.035

Dialdehydes undergo 'radical then aldol' cyclization cascades upon treatment with SmI₂, generating four contiguous stereocenters with high diastereocontrol. The scope of the process has been explored and the cascade has been extended to also in

Full text of DOI:10.1016/j.tet.2009.09.035

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