
Tetrahedron Letters p. 3437 - 3440 (1988)
Update date:2022-08-05
Topics:
Mansour, Tarek S.
In the presence of Hunig's base and anhydrous magnesium chloride, benzoylacetonitrile (1) reacts with 2-haloketones and -esters to give C-alkylated products which may cyclize to polysubstituted furans whereas with acid chlorides O-acylated products are obtained as separable mixtures of E and Z isomers.
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(1955)