CHEMISTRY OF CYCLOPROPYLACYLSILANES I. α-FUNCTIONALIZED ACYLSILANE REAGENTS FOR THE CYCLOPROPANATION OF ELECTROPHILIC ALKENES

DOI: 10.1016/S0040-4020(01)86660-6

Source and publish data:

Tetrahedron p. 4113 - 4134 (1988)

Update date:2022-07-31

Topics: Reagents Alkene Functionalized Cyclopropanation Chemistry Experimental Electrophilic Cyclopropyl

Authors:

Nowick, James J.

Danheiser, Rick L.

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Article abstract of DOI:10.1016/S0040-4020(01)86660-6

Two classes of α-functionalized acylsilane reagents have been developed to effect the cyclopropanation of electrophilic alkenes.The lithium enolate derivatives of the α-haloacylsilanes 14, 15, and 17 react with a wide variety of electron-deficient olefins

Full text of DOI:10.1016/S0040-4020(01)86660-6

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