Tetrahedron p. 7413 - 7426 (1988)
Update date:2022-08-03
Topics:
Zoller, Uri
Lithio-imidazolium salts 10, generated in-situ from N'N-dimethylimidazolium salts 9, readily undergo sulfonylation with sulfur dioxide, sulfines, N-sulfinylamines, and thiirane.The resulting zwitterionic species 4 fragment thermally to yield the corresponding imidazolium thione 5 with the hypervalent three-membered thiaheterocyclic intermediates 3 connecting 4 and 5 on the reaction surface.The non-linear cheletropic fragmentation of these relatively stable hypervalent sulfuranes appears to be general for this class of compounds (3 or 4), and the experimental results are in accord with theoretical considerations.
View MoreHangzhou Share Chemical Co., Ltd(expird)
Contact:+86-57187093700
Address:Hang Xing Road
Taixing Joxin Bio-tec Co.,Ltd.
website:http://www.joxbio.com
Contact:86-523-87558858 87612088
Address:No.88, chengdong industrial park
Shandong Ailitong New Material Co.,Ltd
Contact:+86-536-3226266
Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
shanghai tuomiao chemicial co.,ltd.
website:https://www.tuomiaochem.com/
Contact:021 - 59853336
Address:shanghai
Puyang Huicheng Electronic Material Co., Ltd
website:http://huichengchem.weba.testwebsite.cn/index_en.html
Contact:+86-393-8910800
Address:West Section Shengli Road, Puyang457000, China
Doi:10.1016/j.dyepig.2009.07.014
(2010)Doi:10.1021/acs.oprd.8b00444
(2019)Doi:10.1039/c6ta03453e
(2016)Doi:10.1021/jo01220a009
(1938)Doi:10.1021/om901068f
(2010)Doi:10.1016/S0040-4039(00)82296-0
(1988)
