PHOTOCHEMICAL REACTIVITY OF SPIRODIENONE OBTAINED BY OXIDATION OF BIS(2-HYDROXY-3,5-DI-T-BUTYLPHENYL)METHANONE

DOI: 10.1016/S0040-4039(00)80843-6

Source and publish data:

Tetrahedron Letters p. 5673 - 5676 (1988)

Update date:2022-07-30

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Authors:

Izuoka, Akira

Miya, Shinji

Sugawara, Tadashi

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Article abstract of DOI:10.1016/S0040-4039(00)80843-6

Bis(2-hydroxy-3,5-di-t-butylphenyl)methanone (1) was found to give spirodienone derivative (3) under oxidative condition.UV irradiation of 3 afforded dibenzofuran derivative (5) through an α-fission of cyclohexa-2,4-dienone, accompanied by a loss of CO2.

Full text of DOI:10.1016/S0040-4039(00)80843-6

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