Chemistry Letters p. 247 - 250 (1989)
Update date:2022-08-05
Topics:
Takahashi, Kazuhiko
Sato, Hisao
Mikami, Koichi
Nakai, Takeshi
A new and stereoselective approach to cyclopentanoid synthesis is described.The key step is the thermal intramolecular ene reaction of 4-carboxymethyl-7-benzyloxy-5-heptanal, prepared by the Claisen rearrangement, to afford 2,3-disubstituted cyclopentanol derivative in a highly stereoselective fashion.
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Doi:10.1016/S0040-4020(01)81306-5
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