THE STEREOSELECTIVITY OF RING-OPENING OF 3-SUBSTITUTED CYCLOPROPENES AND INTERMOLECULAR TRAPPING OF DERIVED VINYLCARBENES

DOI: 10.1016/S0040-4039(00)82291-1

Source and publish data:

Tetrahedron Letters p. 6149 - 6152 (1988)

Update date:2022-07-30

Topics: Stereoselectivity Ring-Opening Cyclopropenes

Authors:

Al-Dulayymi, Juma'a

Baird, Mark S.

Clegg, William

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Article abstract of DOI:10.1016/S0040-4039(00)82291-1

Cyclopropene (4, X = Ph) reacts with 2,3-dimethylbut-2-ene or methylacrylate to produce predominantly the cyclopropanes (5k) and (5m) with an E-stereochemistry at the alkene and, in the latter case, cis-stereochemistry of the alkene and ester about the cy

Full text of DOI:10.1016/S0040-4039(00)82291-1

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