Journal of Organic Chemistry p. 3588 - 3596 (1989)
Update date:2022-08-04
Topics:
Flippin, Lee A.
Brown, Peter A.
Jalali-Araghi, Keyvan
The addition reactions of 3,4-epoxy-1-alkanol derivatives were studied using Li(CH3)2Cu (ether, 0 deg C) and 2:1 (CH3)3Al-n-BuLi or 2:1 (C2H5)3Al-n-BuLi (hexane, 0 deg C).In all cases Li(CH3)2Cu showed a small (2-3:1) preference for C(4) addition over C(3
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