SYNTHESES OF BICYCLIC 1,2-DIOLS VIA THE RING-EXPANSION OF BRIDGEHEAD ALDEHYDES OF BICYCLOOCTANE AND BICYCLONONANES WITH BENZOYL TRIFLATE

DOI: 10.1016/S0040-4020(01)81430-7

Source and publish data:

Tetrahedron p. 5681 - 5694 (1988)

Update date:2022-08-04

Topics:

Authors:

Takeuchi, Ken'Ichi

Ikai, Keizo

Yoshida, Masayasu

Tsugeno, Akio

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Article abstract of DOI:10.1016/S0040-4020(01)81430-7

Bridgehead aldehydes of bicyclo<3.2.1>octane (11a), bicyclo<3.3.1>nonane (12a), and bicyclo<3.2.2>nonane (13a) have been subjected to acylative ring-expansion by using benzoyl trifluoromethanesulfonate (triflate) to give mixtures of two or three bicyclic

Full text of DOI:10.1016/S0040-4020(01)81430-7

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