Journal of Organic Chemistry p. 3652 - 3660 (1989)
Update date:2022-09-26
Topics:
Wadsworth, Donald H.
Weidner, Charles H.
Bender, Steven L.
Nuttall, Robert H.
Luss, Henry R.
The oxidation products of 1- and 3-indolizinols have been investigated and characterized.A variety of stabilized indolizinols form stable, crystalline free radicals by one-electron oxidations.Both 7-H and 7-CH3 substituted indolizinols, when subjected to the exhaustive aerial or benzoquinone oxidation, from the oxidatively coupled 1,1'- or 3,3'-dioxo-7,7'-bisindolizines.Two-electron oxidation of indolizinols formed oxoindolizinium ions.
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