DIOXOLANNES CHIRAUX DERIVES DE L'ACIDE (-)SHIKIMIQUE. DETERMINATION PAR RMN 1H 2D ET 13C DE LA CONFIGURATION DU CENTRE ASYMETRIQUE CREE

DOI: 10.1016/S0040-4039(00)80545-6

Source and publish data:

Tetrahedron Letters p. 4555 - 4558 (1988)

Update date:2022-08-04

Topics:

Authors:

Delfourne, E.

Gorrichon, L.

Zedde, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80545-6

Chiral dioxolans have been synthesized from (-)methyl shikimate and β-ketoesters in order to mimic the enolization process postulated in the enzyme dehydroquinate hydrolyase mechanism.We expect the (R) isomers to be better recognized by the enzyme.The configuration of the newly created asymmetric center in the dioxolan has been determined by 2D ¹H and ¹³C NMR

Full text of DOI:10.1016/S0040-4039(00)80545-6

Products guided by the article

Product name:(2R,3aR,7R,7aS)-7-Hydroxy-2-methyl-2-phenoxycarbonylmethyl-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester

Cas No:121786-65-0

R&D Labs maybe for 121786-65-0

Arromax Pharmatech Co.,Ltd

website:http://www.arromax.com

Contact:+86-0512-62959601 skype:aimmezhang

Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
shandong lukang animal & plant drug trading co.,ltd.

Contact:15853765968

Address:floor 9, lukang ,jingying building,#173,taibai building west road,jining city,shandong,china
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )

Relevant to this article

Diels-Alder Reactions Involving cis-1,2-Isopropylidenedioxycyclohexa-3,5-diene and Enzymatic Resolution of One of the Adducts

Doi:10.1039/c39880001628
(1988)
1-Bromo-2-ethoxycyclolithium: A Synthetic Equivalent of 2-Lithio or 3-Lithiopropenal. Application to the Synthesis of Juvenile Hormone (JH-II), β-Sinensal, and Jasmonoids.

Doi:10.1246/bcsj.57.1935
(1984)
An expeditious method for the preparation of 2-hydroxy-1,4-dioxane and Its Use in reductive alkylation of amines

Doi:10.1055/s-0029-1217101
(2010)
Preparation of new nitrogen-bridged heterocycles 67.¹ syntheses of α,α′-bis[(thieno[3,4-b]indolizin-3-yl)thio]-o-, m-, and p-xylene derivatives and their conformational structures

Doi:10.1248/cpb.57.1385
(2009)
Stepwise and selective carborane substitution in the B(3,6) positions of a 16 e CpCo half-sandwich complex containing a chelating ortho -carborane-1,2-dithiolate ligand

Doi:10.1021/ic1001804
(2010)
Synthesis of Hydroxylated 1-Azabicyclo<3.1.0>hexane and Prolinol Derivatives by Stereo- and Regiocontrolled Staudinger Aminocyclization. Application to the Nonproteinogenic Amino Acid (2S,3S,4S)-3-Hydroxy-4-methylproline (HMP) and Its Enantiomer

Doi:10.1021/ja00201a033
(1989)

Article Doi