Journal of Organic Chemistry p. 3514 - 3515 (1989)
Update date:2022-08-05
Topics:
Posner, Gary H.
Shulman-Roskes, Ellen M.
In THF at -78 deg C, lithio enolates of several different acyclic and cyclic carboxylate esters react cleanly with 2 equiv of an acrylate ester via a Michael-Michael-Dieckmann cyclization sequence to form polyfunctionalized cyclohexanones in 45-72percent overall yields; this process represents useful, controlled interruptions of polymerization reactions.
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Doi:10.1080/15533170903095011
(2009)Doi:10.1021/ja102041s
(2010)Doi:10.1016/j.bmcl.2009.12.064
(2010)Doi:10.1021/jo01313a033
(1980)Doi:10.1016/S0040-4039(00)96340-8
(1987)Doi:10.1021/ja00199a025
(1989)
