Transition-metal Carbonyl Derivatives of the Germanes. Part 17. Tetracarbonylgermyl(trimethylgermyl)iron, , its Conversion into 2>, and hence to (characterised by X-Ray Crystallography) via

DOI: 10.1039/DT9880002629

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2629 - 2634 (1988)

Update date:2022-08-02

Topics: X-ray crystallography Experimental terms

Authors:

Anema, Skelte G.

Audett (nee Christie), Judy A.

Mackay, Kenneth M.

Nicholson, Brian K.

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Article abstract of DOI:10.1039/DT9880002629

The synthesis and spectroscopic characterisation of the mixed germane derivative (3) are described.This compound eliminates GeMe3H to give quantitatively <2> (4), which has a Fe2Ge2 four-membered ring.The GeH2 units of (4) react with , eliminating H2 and CO, to give (7).Quantitative loss of CO from (7) gives (8) which has been shown by an X-ray crystal structure determination to contain linked Co2Ge and Fe2Ge triangles.

Full text of DOI:10.1039/DT9880002629

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