Tetrahedron Letters p. 1289 - 1292 (1989)
Update date:2022-08-04
Topics:
Citterio, Attilio
Cerati, Anna
Sebastiano, Roberto
Finzi, Claudia
Santi, Roberto
Iron (III) salts (perchlorate and nitrate nonahydrate) in acetonitrile or acetic anhydride at 0-50 deg C oxidize the α-position of malonic esters efficiently via the corresponding radicals.In the presence of olefins and aromatics, inter- and intramolecular free radical chain or oxidative additions are observed.
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