p-(Tricyanovinylidene)phenylhydrazones. Nucleophilic Attack on Carbon-Carbon Double Bonds

DOI: 10.1007/BF00810281

Source and publish data:

Monatshefte fur Chemie p. 1375 - 1384 (1988)

Update date:2022-08-04

Topics:

Authors:

Bruni, Paolo

Cardillo, Barbara

Tosi, Giorgio

Bocelli, Gabriele

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00810281

The dispacement of a -CN group in p-(tricyanovinylidene)phenylhydrazones, induced by amines, is investigated.The rate of the reaction is dependent on the polarity of the solvent and the observed second-order rate coefficients k²_obs for the -CN displacement increase with the amine concentration.A X-ray analysis of one of the substituted compounds is also reported. - Keywords: Hydrazones; Nucleophilic substitution reactions; Kinetics of substitution reactions

Full text of DOI:10.1007/BF00810281

Products guided by the article

Product name:2-[[4-(N'-Benzhydrylidene-hydrazino)-phenyl]-(4-methoxy-phenylamino)-methylene]-malononitrile

Cas No:122127-96-2

R&D Labs maybe for 122127-96-2

PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china

Relevant to this article

Synthesis of 3-substituted 2-amino-1-hydroxy-1H-Indole-5, 6-dicarbonitriles

Doi:10.1007/s10593-012-1010-6
(2012)
Discovery of benzhydrol-oxaborole derivatives as Streptococcus pneumoniae leucyl-tRNA synthetase inhibitors

Doi:10.1016/j.bmc.2020.115871
(2021)
2,2-Bis(ethoxycarbonyl)vinyl (BECV) as a versatile amine protecting group for selective functional-group transformations

Doi:10.1002/chem.200902054
(2010)
Studies directed toward the design of orally active renin inhibitors. 1. Some factors influencing the absorption of small peptides

Doi:10.1021/jm00056a005
(1993)
1,3-Benzodithiole-1,1,3,3-tetraoxide (BDT) as a versatile methylation reagent in catalytic enantioselective Michael addition reaction with enals

Doi:10.1016/j.tetlet.2010.01.102
(2010)
Catalytic asymmetric 1,4-additions of β-keto esters to nitroalkenes promoted by a bifunctional homobimetallic Co₂-schiff base complex

Doi:10.3390/molecules15010532
(2010)

Article Doi