Journal of Organic Chemistry p. 4333 - 4337 (1990)
Update date:2022-09-26
Topics:
Chenier, Philip J.
Southard, Dale A.
The title compound 8 has been synthesized in situ from dibromide 18 via debromination with tert.-butyllithium in THF at -78 deg C.In the presence of diphenylisobenzofuran (27), the Diels-Alder adduct 29 is formed.Cyclopropene 8 was also trapped with diene 28 to give a second adduct 30.The synthetic methodology for precursor dibromide 18 appears to have general application for other similar highly strained tricyclic cyclopropenes.
View MoreNeworld Chemical Co., Ltd Shanghai(expird)
Contact:+86-21-62202658
Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
Hebei Kangtai Pharmaceutical Co.,Ltd
Contact:+86-0317-3512963
Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
chengdu firsterchem Pharmaceutical Co., Ltd.
Contact:028-66825849
Address:chengdu
Contact:86-25-51817806
Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Doi:10.1016/j.tetasy.2010.01.008
(2010)Doi:10.1007/BF00953741
(1989)Doi:10.1016/j.ejmech.2009.12.057
(2010)Doi:10.3762/bjoc.7.93
(2011)Doi:10.1016/S0040-4020(01)89798-2
(1988)Doi:10.1021/jo502574u
(2015)
