Journal of Organic Chemistry p. 4333 - 4337 (1990)
Update date:2022-09-26
Topics:
Chenier, Philip J.
Southard, Dale A.
The title compound 8 has been synthesized in situ from dibromide 18 via debromination with tert.-butyllithium in THF at -78 deg C.In the presence of diphenylisobenzofuran (27), the Diels-Alder adduct 29 is formed.Cyclopropene 8 was also trapped with diene 28 to give a second adduct 30.The synthetic methodology for precursor dibromide 18 appears to have general application for other similar highly strained tricyclic cyclopropenes.
View MoreContact:+86-371-55981030
Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Yangzhou Siyu Chemical Co.,Ltd.
Contact:+86-514-87325867 13358126196
Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Nanjing Fubang Chemical Co.,Ltd
Contact:+86-25-83179199
Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Contact:86 513 85512619
Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
Contact:+86-519-86623222
Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Doi:10.1016/j.tetasy.2010.01.008
(2010)Doi:10.1007/BF00953741
(1989)Doi:10.1016/j.ejmech.2009.12.057
(2010)Doi:10.3762/bjoc.7.93
(2011)Doi:10.1016/S0040-4020(01)89798-2
(1988)Doi:10.1021/jo502574u
(2015)
