Stereoselectivity, Non-stereospecificity, and the Lifetime of the Thiometaphosphonimidate Intermediate formed in the Reactions of the Diastereoisomers of a Phosphonamidothioic Chloride with t-Butylamine

DOI: 10.1039/c39880001256

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1256 - 1257 (1988)

Update date:2022-08-03

Topics:: Authors:

Harger, Martin J. P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880001256

Both diastereoisomers of t-BuP(S)(Cl)NHR react with t-BuNH2 (0.25 M) in an aprotic solvent to give the same mixture of the diastereoisomers of t-BuP(S)(NHt-Bu)NHR (no stereospecificity), but the diastereoisomer ratio of the product (stereoselectivity) increases from 57 : 43 (MeCN) to 80 : 20 (cyclohexane) as the polarity (ε_τ) of the solvent is reduced.

Full text of DOI:10.1039/c39880001256

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:N-<(S)-α-phenylethyl>-P-t-butylphosphonamidothioic acid

Cas No:122183-07-7

R&D Labs maybe for 122183-07-7

Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui
Hangzhou Ocean Chemical Co., Ltd.

website:http://www.hzoceanchem.com

Contact:+86-571-88025872, 28272092, 28272096

Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone

Relevant to this article

Synthesis, carbonic anhydrase I and II inhibition studies of the 1,3,5-trisubstituted-pyrazolines

Doi:10.1080/14756366.2016.1244533
(2017)
Doi:10.1016/S0277-5387(00)86441-4
(1989)
PYRROLES FROM KETOXIMES AND ACETYLENE. 38. NEW REPRESENTATIVES OF TRIFLUOROACETYLPYRROLES. SYNTHESIS AND TRANSFORMATIONS

Doi:10.1007/BF00472615
(1989)
Stereocontrolled construction of quaternary stereocenters by inter- and intramolecular nitro-michael additions catalyzed by bifunctional thioureas

Doi:10.1002/adsc.201000612
(2010)
THERMAL BEHAVIOUR OF ARYL γ-HALOPROPARGYL ETHERS

Doi:10.1016/0040-4020(89)80058-4
(1989)
Doi:10.1002/macp.1959.020290107
(1959)

Article Doi

Stereoselectivity, Non-stereospecificity, and the Lifetime of the Thiometaphosphonimidate Intermediate formed in the Reactions of the Diastereoisomers of a Phosphonamidothioic Chloride with t-Butylamine

DOI: 10.1039/c39880001256

Source and publish data:

Authors:

Article abstract of DOI:10.1039/c39880001256

Full text of DOI:10.1039/c39880001256

Products guided by the article

R&D Labs maybe for 122183-07-7

Relevant to this article

Hot Product