An enantioselective synthesis of (+)-bostrycin leading to a revision of the absolute configuration of its natural antipode

DOI: 10.1016/S0040-4020(01)85591-5

Source and publish data:

Tetrahedron p. 4711 - 4732 (1990)

Update date:2022-07-31

Topics: Enantioselective synthesis Absolute Configuration Revision

Authors:

Larsen, David S.

Stoodley, Richard J.

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Article abstract of DOI:10.1016/S0040-4020(01)85591-5

An asymmetric Diels-Alder reaction, involving the protected naphthopurpurin (4) and the D-glucose-derived diene (9a), is used to assemble compound (22), which is transformed by way of compounds (26), (27) and (28) into (+)-bostrycin (3). An X-ray analysis

Full text of DOI:10.1016/S0040-4020(01)85591-5

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