Formation of a Phospha-alkyne via Migration of the Phenyl Group from Phosphorus to Carbon

DOI: 10.1246/cl.1988.1733

Source and publish data:

Chemistry Letters p. 1733 - 1734 (1988)

Update date:2022-08-05

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Authors:

Yoshifuji, Masaaki

Niitsu, Takashi

Inamoto, Naoki

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Article abstract of DOI:10.1246/cl.1988.1733

E-2-Chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-ethylene was allowed to react with t-butyllithium as a base to give 2-(2,4,6-tri-t-butylphenyl)-1-phospha-acetylene, suggesting the generation of a phosphorus analogue of isonitrile followed by migration of

Full text of DOI:10.1246/cl.1988.1733

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