STEPWISE REACTIONS OF DIMETHYLSILYL ACETYLENES WITH OCTACARBONYLDICOBALT

DOI: 10.1246/cl.1989.293

Source and publish data:

Chemistry Letters p. 293 - 296 (1989)

Update date:2022-08-05

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Authors:

Kotani, Sonae

Matsumoto, Toshihiro

Yamaguchi, Hidemasa

Shiina, Kyo

Sonogashira, Kenkichi

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Article abstract of DOI:10.1246/cl.1989.293

Treatment of bis(dimethylsilyl)acetylene 1 with more than two molar amount of octacarbonyldicobalt in cyclohexane gave the complex <(CO)4CoSiMe2CC-SiMe2Co(CO)4>Co2(CO)6, while treatment of 1 with one or 1.5 molar amount of octacarbonyldicobalt produced th

Full text of DOI:10.1246/cl.1989.293

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