Tetrahedron Letters p. 2473 - 2476 (1989)
Update date:2022-09-26
Topics:
Moss, Robert A.
Ho, Guo Jie
Wilk, Bogdan K.
The decomposition of cyclopropylmethyloxychlorodiazirine in MeCN proceeds via N2 and CO loss, mainly to tight cyclopropylcarbinyl cation-chloride anion pairs that collapse to C4 chlorides with substantial skeletal and label retention; the ion pairs can be intercepted by ethanol with less skeletal retention.
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Doi:10.1021/ja00201a052
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