Angewandte Chemie - International Edition p. 2389 - 2392 (2010)
Update date:2022-08-05
Topics: Isolation and Purification Reaction Conditions Stereochemical Control Substrate Selection Selection of Enzyme
Lehwald, Patrizia
Richter, Michael
Mueller, Michael
Roehr, Caroline
Liu, Hung-Wen
(Figure Presented) Happy new YerE: The first example of the title reaction is presented using a ThDPdependent enzyme catalyst. The substrate tolerance of the enzyme is very broad and includes cyclic and open-chain ketones, as well as diketones and a- and β-ketoesters as acceptor substrates. The absolute configurations of two enzymatic products were determined by single-crystal structure analysis.
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(1999)
