The chiral alcohol auxiliary, attached to the solid support, will influence the stereochemistry of the reaction. It can guide the nucleophilic addition to the ketene to obtain the desired stereochemical outcome.
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(RS)-(3-benzyloxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)acetic acid tert-butyl ester
Silane, trimethyl[(1E)-2-[(R)-(4-methylphenyl)sulfinyl]ethenyl]-
Benzaldehyde
Toluene
(4S,4aS,8aS)-4-{[tert-butyl(dimethyl)silyl]oxy}-7,7-dimethoxy-4a-methyloctahydronaphthalen-1(2H)-one
3-Pyridinol,4-methoxy-(9CI)
(R,E)-3-benzylamino-5-phenyl-4-penten-1-ol
methyl 3-O-(2’,3’,4’,6’-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-galactopyranoside
1-(7-Hydroxy-5-methoxy-2,2-dimethyl-2H-chromen-8-yl)ethanone
2
3-Methyl-2-butenal
(E)-2,2,2-trifluoro-N-(3-oxo-3-(2-oxooxazolidin-3-yl)-1-phenylprop-1-en-2-yl)acetamide
2-(r-2-phenyl-c-4-(3',4'-methylenedioxyphenyl)-1,3-dioxan-c-5-yl)-ethanol
C28H50O4Si2
C6(13)C2H14O2
(1S,2R,4S)-4-methyl-benzenesulfinic acid {1-[2-(4-methoxy-benzyl)-1,1-dioxo-1λ6-isothiazolidin-5-yl]-2,2-dimethyl-propyl}-amide
(S)-tert-butyl 2-amino-3-(2-bromo-5-hydroxyphenyl)propanoate
((2S,4R)-4-Carboxy-2-methyl-pentyl)-triphenyl-phosphonium; iodide
2-Cyclohexen-1-one, 4-(hydroxymethyl)-, (4R)-
4-cyclohexyl-4-hydroxy-3-methyl-2-butanone
iodomethane
2,5-Dihydro-2,5-dimethoxyfuran
ethyl 3E-<(1R,2S)-2-phenyl-1-cyclopropyl>prop-1-enoate
fumagillol
(2R,4R)-3-Benzyl-2-phenethyl-4-phenyl-oxazolidine
3-[2-(1,2-dihydroxy-2-phenyl-ethyl)-oxazol-4-yl]-3-triethylsilanyloxy-thiopropionic acid S-tert-butyl ester
(1S,2R,5S)-5-(1-hydroxypropan-2-yl)-2-methyl-3-cyclohexenol tetrahydropyranyl ether
2H-1,2,4-Benzothiadiazine, 3,4-dihydro-3-(phenylmethyl)-, 1,1-dioxide
l-menthyl-2-methyl-2-phenylbutanoate
methyl 2-deoxy-5-O-(4-methoxyphenyl)diphenyl-D-methyl-erythro-pento-D-furanoside
3-methylphenethyl bromide
(1S,2S)-2-(Diphenyl-phosphinoyl)-1-phenyl-butan-1-ol
5H-Inden-5-one, 1,2,3,3a,4,7a-hexahydro-7a-methyl-, trans-
(+/-)-(2-{[(2-methoxyethoxy)methoxy]methyl}-1-phenyl-cycloprop-2-en-1-yl)-methanol
(3S,4S)-5-(tert-butyldiphenylsilyloxy)-4-methoxymethoxy-3-(trichloromethylcarbonylamino)pent-1-ene
(1S)-1,3-dimethyl-2-(2-methoxyethyl)-2-cyclohexene-1-carboxylic acid methyl ester
(6R)-2-<(R)-2-hydroxy-2-phenylacetyl>-6-<(S)-5-methoxycarbonyl-2-oxo-pyrrolidine-1-yl>-3,6-dihydro-2H-1,2-oxazine
(R)-3-(benzyloxymethyl)-3-methyl-1-phenylpentan-1-one
(2R,5Z,8Z)-2-(N-o-tolylaminooxy)undeca-5,8-dien-1-ol
(R)-1-(tert-butylsulfonyl)-2-phenylaziridine
2-(4-methoxy-2-vinylphenyl)cyclopentan-1-one
ethyl ester of 10-oxo-4E-decenoic acid
(4S,5S)-6-Benzyloxy-1-[(2R,4S,6S,8R,9S)-8-((S)-sec-butyl)-4-(tert-butyl-dimethyl-silanyloxy)-9-methyl-1,7-dioxa-spiro[5.5]undec-10-en-2-yl]-4-(2-methoxy-ethoxymethoxy)-5-methyl-hexan-3-one
5-benzoyl-4-(3-chlorophenyl)-2-phenoxy-2a-phenyl-2a,3,4,5-tetrahydroazeto[1,2-a][1,5]benzodiazepin-1(2H)-one
(R)-2,2-DIMETHYL-OXAZOLIDINE-3,4-DICARBOXYLIC ACID 3-TERT-BUTYL ESTER
methyl 6-amino-6-deoxy-α-D-glucopyranoside
