
Bulletin of the Chemical Society of Japan p. 519 - 523 (1989)
Update date:2022-09-26
Topics:
Kanemoto, Shigekazu
Saimoto, Hiroyuki
Oshima, Koichiro
Utimoto, Kiitiro
Nozaki, Hitosi
Sereval polymer supported catalysts are prepared by treatment of Nafion 551 (abbreviated NAFK below) with metal salts.Cr/NAFK and Ce/NAFK found to be effective catalysts for the dehydrogenative oxidation of alcohols to the corresponding ketones by means of t-butyl hydroperoxide.Selective oxidation of secondary alcohols in the presence of primary ones was performed using a Ce/NAFK-NaBrO3 system.
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